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Key Elements of Green Chemistry
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Lucian Lucia, North Carolina State University
Copyright Year: 2018
Publisher: North Carolina State University
Language: English
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Reviewed by Debasish Bandyopadhyay, Assistant Professor, University of Texas Rio Grande Valley on 12/22/21
The book presents the major concepts of green chemistry in six chapters. read more
Comprehensiveness rating: 5 see less
The book presents the major concepts of green chemistry in six chapters.
Content Accuracy rating: 5
The content is accurate and to the point.
Relevance/Longevity rating: 5
All the materials presented in this book are updated.
Clarity rating: 5
The text is written in simple language that should be helpful for the readers to understand the topic.
Consistency rating: 4
The six chapters are well-aligned, and the whole concept of green chemistry has been thoughtfully presented in this book.
Modularity rating: 5
The text is easily and readily divisible into smaller reading sections that can be assigned at different points within the course. Under each chapter, there are several headings sections and subsections. The text is not overly self-referential and should be quickly reorganized and realigned with various subunits of a course without presenting much disruption to the reader.
Organization/Structure/Flow rating: 4
In each chapter, their sections and sub-sections have been organized stepwise.
Interface rating: 4
The text is free of significant interface issues, including navigation problems, distortion of images/charts, and any other display features that may distract or confuse the reader.
Grammatical Errors rating: 5
There are no significant grammatical errors.
Cultural Relevance rating: 5
The text is not culturally insensitive or offensive in any way.
Although the book's target readers are green chemists, it is an excellent reference book also for toxicologists, chemical engineers, pharmacologists, and biochemists. The author has successfully correlated the green chemistry parameters with the real world. For example, the author included the incidents of burning oil and debris that collected on the surface of the Cuyahoga River (Cleveland), the thalidomide issue etc. The discussion on the LCA software, the globally harmonized system (GHS) that attempts to categorize the general types of threats in society, specifically, is fascinating. The concept of different hazards such as carcinogens, mutagens, teratogens, tumor promoters, corrosives, neurotoxins, lachrymators has added special value to this book. The lethal dose of everyday things like water to Vit C provides real-world examples. The author has brilliantly correlated the chemistry world with the business world by the dual meaning of ‘solvent’. Discussion on alternative solvents like green biobased solvent methyl soyate, eutectic mixture, microemulsion, etc., are fascinating. Combinatorial chemistry and organic reaction mechanism part will undoubtedly draw attention to the organic chemistry students. In the last chapter, the classification of organic reactions and their correlation with green chemistry is eloquent. The images are significant. The author referenced each image so that curious readers could go more over it. At the end of each chapter, the review questions will insist the readers rethink the subject matter. A little comicalness throughout the book will keep the readers smiling.
Table of Contents
- Chapter 1: Principles Of Green Chemistry
- Chapter 2: Life-Cycle Analysis
- Chapter 3: Hazards
- Chapter 4: Alternative Solvents
- Chapter 5: Alternative Reagents
- Chapter 6: Reaction Types, Design, And Efficiency
- Index Of Terms
Ancillary Material
About the book.
Green chemistry, in addition to being a science, it is also a philosophy and nearly a religion. Attendance at American Chemical Society Green Chemistry & Engineering Conferences will instill such an ideal into any attendant because of the nearly universal appeal and possibilities in this novel approach to radicalizing the business of doing science and engineering.
About the Contributors
Lucian Lucia currently serves as an Associate Professor in the Departments of Forest Biomaterials and Chemistry and as a faculty in the programs of Fiber & Polymer Science and Environmental Sciences at North Carolina State University. His laboratory, The Laboratory of Soft Materials & Green Chemistry, probes fundamental materials chemistry of biopolymers. He received his Ph.D. in organic chemistry from the University of Florida under Professor Kirk Schanze for modeling photoinduced charge separation states of novel Rhenium (I)-based organometallic ensembles as a first order approximation of photosynthesis. He began his professional career as an Assistant Professor at the Institute of Paper Science and Technology at the Georgia Institute of Technology examining the mechanism of singlet oxygen’s chemistry with lignin & cellulose. A large part of his recent work has been focused on the chemical modification of cellulosics for biomedical applications. He teaches From Papyrus to Plasma Screens: Paper & Society (PSE 220), Principles of Green Chemistry (PSE / CH 335), and is the graduate supervisor for the Forest Biomaterials Seminar Series (WPS 590 / 790) while providing workshops in Wood Chemistry and Green Chemistry at Qilu University of Technology in PR China. He has co-founded and co-edits an open-access international research journal, BioResources, dedicated to original research articles, reviews, and editorials on the fundamental science & engineering and advanced applications of lignocellulosic materials.
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Green chemistry: An introductory text
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Green Chemistry
Introduction, Application and Scope
- © 2022
- Vinod K. Tiwari 0 ,
- Abhijeet Kumar 1 ,
- Sanchayita Rajkhowa 2 ,
- Garima Tripathi 3 ,
- Anil Kumar Singh 4
Department of Chemistry, Banaras Hindu University, Varanasi, India
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Department of Chemistry, Mahatma Gandhi Central University, Motihari, India
Department of chemistry, the assam royal global university, guwahati, india, department of chemistry, t. n. b. college, bhagalpur, india.
- Presents the fundamentals and advances in the area of green chemistry
- Highlights the importance and impact of green approaches over the traditional synthetic method
- Underlines the importance of efficiency enhancement with simultaneous energy demand reduction
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About this book
This book summarizes fundamentals and advanced topics of green chemistry and highlights the importance and impact of green chemistry over traditional synthetic methods. It discusses about the importance and scope of the catalytic protocols in green chemistry and their application in daily life. Alternate green energy approaches discussed in this book underline the importance of efficiency enhancement with simultaneous energy demand reduction by replacing the dependence on non-renewable energy resources. Various topics covered in this book include green solvents, energy-efficient approach for organic synthesis, catalysis, biocatalysis, and green approach in pharmaceutically important molecules and drugs. The book will be a valuable reference for beginners, researchers, and professionals interested in sustainable green chemistry and their scope in allied fields.
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Table of contents (9 chapters)
Front matter, green chemistry: introduction to the basic principles.
- Vinod K. Tiwari, Abhijeet Kumar, Sanchayita Rajkhowa, Garima Tripathi, Anil Kumar Singh
Energy-Efficient Process in Organic Synthesis
Green solvents: application in organic synthesis, growing impact of ionic liquids in heterocyclic chemistry, growing impact of ionic liquids in carbohydrate chemistry, catalysis: application and scope in organic synthesis, organocatalysis: a versatile tool for asymmetric green organic syntheses, enzymes in organic synthesis, application of green chemistry: examples of real-world cases, authors and affiliations.
Vinod K. Tiwari
Abhijeet Kumar, Anil Kumar Singh
Sanchayita Rajkhowa
Garima Tripathi
About the authors
Dr. Abhijeet Kumar is currently working as Assistant Professor of Organic Chemistry at Mahatma Gandhi Central University (MGCU), Bihar, India. He has received his B.Sc. and M.Sc. degrees in Chemistry from Banaras Hindu University in 2006 and 2008, respectively. In 2016, he completed his doctoral research from Indian Institute of Technology (IIT), Kanpur, with Prof. M. L. N. Rao, where he received research training in the development of metal-catalyzed cross-coupling reactions using organobismuth reagents as green organometallic reagents. He received ‘Visiting Faculty Fellowship’ to carry out research work at JNCASR, Bangalore. He has been involved in teaching the green chemistry to the UG/PG courses at MGCU since last four years. He has published several peer-reviewed publications and also contributed few book chapters of high repute.
Dr. Anil Kumar Singh is currently working as Assistant Professor in the Department of Chemistry, Mahatma Gandhi Central University, Bihar. He has completed his B.Sc. and M.Sc. degrees in Chemistry from Banaras Hindu University in 2009 and 2011, respectively. He earned his Ph.D. degree in 2015 from University of Delhi, New Delhi, India, under the supervision of Dr. Brajendra Kumar Singh. He has published several research articles of national and international repute. He has been awarded with prestigious Erasmus Mundus-Action 2 fellowship during his Ph.D. and worked at Ghent University, Belgium (Mentor: Prof. Johan van der Eycken).
Bibliographic Information
Book Title : Green Chemistry
Book Subtitle : Introduction, Application and Scope
Authors : Vinod K. Tiwari, Abhijeet Kumar, Sanchayita Rajkhowa, Garima Tripathi, Anil Kumar Singh
DOI : https://doi.org/10.1007/978-981-19-2734-8
Publisher : Springer Singapore
eBook Packages : Chemistry and Materials Science , Chemistry and Material Science (R0)
Copyright Information : The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd. 2022
Hardcover ISBN : 978-981-19-2733-1 Published: 03 September 2022
Softcover ISBN : 978-981-19-2736-2 Published: 04 September 2023
eBook ISBN : 978-981-19-2734-8 Published: 02 September 2022
Edition Number : 1
Number of Pages : XX, 376
Number of Illustrations : 449 b/w illustrations, 38 illustrations in colour
Topics : Green Chemistry , Inorganic Chemistry , Organic Chemistry , Catalysis
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Green Chemistry: Principles and Case Studies
Green chemistry as a discipline is gaining increasing attention globally, with environmentally conscious students keen to learn how they can contribute to a safer and more sustainable world. Many universities now offer courses or modules specifically on green chemistry – Green Chemistry: Principles and Case Studies is an essential learning resource for those interested in mastering the subject.
Providing a comprehensive overview of the concepts of green chemistry this book engages students with a thorough understanding of what we mean by green chemistry and how it can be put into practice. Structured around the well-known 12 Principles, and firmly grounded in real-world applications and case-studies, this book shows how green chemistry is already being put into practice and prepare them to think about how they can be incorporated into their own work.
Targeted at advanced undergraduate and first-year graduate students with a background in general and organic chemistry, it is a useful resource both for students and for teachers looking to develop new courses.
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F. A. Etzkorn, Green Chemistry: Principles and Case Studies, The Royal Society of Chemistry, 2019.
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Print format, table of contents.
- Front Matter
- Acknowledgements
- The 12 Principles of Green Chemistry
- 1: Prevent Waste p1-22 Abstract Open the PDF Link PDF for 1: Prevent Waste in another window
- 2: Synthetic Efficiency p23-56 Abstract Open the PDF Link PDF for 2: Synthetic Efficiency in another window
- 3: Benign Synthesis p57-90 Abstract Open the PDF Link PDF for 3: Benign Synthesis in another window
- 4: Benign Products p91-124 Abstract Open the PDF Link PDF for 4: Benign Products in another window
- 5: Avoid Auxiliaries p125-168 Abstract Open the PDF Link PDF for 5: Avoid Auxiliaries in another window
- 6: Energy Efficiency p169-207 Abstract Open the PDF Link PDF for 6: Energy Efficiency in another window
- 7: Renewable Feedstocks p208-236 Abstract Open the PDF Link PDF for 7: Renewable Feedstocks in another window
- 8: Avoid Protecting Groups p237-270 Abstract Open the PDF Link PDF for 8: Avoid Protecting Groups in another window
- 9: Catalysis p271-298 Abstract Open the PDF Link PDF for 9: Catalysis in another window
- 10: Degradation or Recovery p299-320 Abstract Open the PDF Link PDF for 10: Degradation or Recovery in another window
- 11: Real-time Analysis p321-352 Abstract Open the PDF Link PDF for 11: Real-time Analysis in another window
- 12: Prevent Accidents p353-378 Abstract Open the PDF Link PDF for 12: Prevent Accidents in another window
- Appendix A: Organic Functional Groups p379-383 Open the PDF Link PDF for Appendix A: Organic Functional Groups in another window
- Appendix B: Organic Mechanism p384-408 Open the PDF Link PDF for Appendix B: Organic Mechanism in another window
- Appendix C: p K a Tables p409-415 Open the PDF Link PDF for Appendix C: p<em>K</em><sub>a</sub> Tables in another window
- Appendix D: Earth Abundance Periodic Table p416-417 Open the PDF Link PDF for Appendix D: Earth Abundance Periodic Table in another window
- Appendix E: Standard Reduction Potentials by Value p418-420 Open the PDF Link PDF for Appendix E: Standard Reduction Potentials by Value in another window
- Appendix F: Solvent Selection Guide p421-422 Open the PDF Link PDF for Appendix F: Solvent Selection Guide in another window
- Appendix G: Selected Bond Dissociation Energies p423-424 Open the PDF Link PDF for Appendix G: Selected Bond Dissociation Energies in another window
- Subject Index p425-447 Open the PDF Link PDF for Subject Index in another window
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GCTLC Library
Welcome to the GCTLC Library. Use the search and filter options below to find green chemistry education resources and curriculum materials from community members from across the world. You can also submit a new resource to the library. For information for authors and reviewers, please consult the Guidelines for Submission and Review of Learning Objects .
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STEMify Your Classroom Supply List
In this lesson, students will develop an evidence-based argument after investigating the product safety, performance, and cost of a variety of cleaning and disinfecting products designed to remove germs. Students will be introduced to principles of sustainable design, life-cycle thinking, and how to identify safer products for certifications.
Except where otherwise noted, this work by Saskia van ...
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USDA BioPreferred Standards Context Lesson Plan
Students will compare the basis of the derivatives for different plastics in order to determine their expected carbon-14 content. They will then compare ratios of carbon-14 to carbon-12 in plastic samples and categorize the sample according to its percent bio-based composition.
Teacher Background Information: This lesson is more of a context design to be used with an existing nuclear chemistry ...
![overview on green chemistry assignment pdf logo with green flask with green gem superimposed on part of flask](https://gctlc.org/sites/default/files/styles/learning_object_library/public/2023-10/gems-logo_3.png.webp?itok=-ncoThsL)
"Greening Up" the Suzuki Reaction
An aqueous Suzuki reaction is described which highlights the facile preparation of a non-steroidal anti-inflammatory (NSAID) drug analog under green conditions. While palladium-catalyzed cross-coupling reactions are common in most modern organic chemistry labs, they are often performed with hazardous solvents and large amounts of corrosive additives. Undertaken at the mid-undergraduate level ...
![overview on green chemistry assignment pdf Title picture for this episode](https://gctlc.org/sites/default/files/styles/learning_object_library/public/2024-03/uc-boulder-cover-image.jpg.webp?itok=Hm2dB7si)
"It's Our Future to Decide" - How a Student & Two Professors Got Green Chemistry into the Curriculum at the Univ. of Colorado
In this episode of Green Chem Essential, with host James Rea: Learn how – and why — a motivated student and two professors at CU Boulder successfully worked to get green chemistry into the curriculum at their school.
Guests in this episode include; Brinn McDowell, Dr. Kathryn Ramirez Aguilar and Dr. Matthew E Wise
![overview on green chemistry assignment pdf logo with green flask with green gem superimposed on part of flask](https://gctlc.org/sites/default/files/styles/learning_object_library/public/2023-10/logo-with-green-flask-with-green-gem-superimposed-on-park-of-the-flask_8.png.webp?itok=7A7jPd0S)
"New" Compounds from Old Plastics: Recycling PET Plastics via Depolymerization. An Activity for the Undergraduate Organic Lab
As landfills begin reaching their capacity and waste generation skyrockets, the world is being forced to take a harder look at recycling. Because it is currently estimated that plastics make up a quarter of landfill space, the recycling of plastics is a hot, current topic.
In this lab, a common plastic, polyethylene terephthalate (PET), will be depolymerized by a simple hydrolysis reaction ...
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"We Are Going To Be Rebels Together" ~ A Look Inside the Univ. of Toronto's Green Chemistry Initiative
For more than 10 years now, the University of Toronto's Green Chemistry Initiative has been a wonderfully creative incubator for green chemistry learning on that campus. In this episode of Green Chem Essential, with host James Rea: Hear how -- and why -- this student-led group works to engage their peers in the science of sustainability.
The interview includes discussion about their annual spring ...
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01 - History and Principles of Toxicology - (Toxicology for Chemists Curriculum - Module 1)
This module serves as a good first introduction to toxicology. In the first part of the module, students will learn and understand: the history of toxicology and its underlying principles; the progression of toxicology as a science; the development of regulatory agencies; key case studies that developed the field; and the paradox of uncertainty. In the second part of the module, students will ...
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02 - Understanding Hazard and Risk (Toxicology for Chemists - Module 2)
This module is an introduction to understanding the principles of hazard and risk. The lectures are designed with a “choose your own adventure” format: you can take any slides and use them in any order to build your lecture! Using these materials, students will understand the basic concepts of hazard, exposure, and risk; be able to perform a simple chemical hazard assessment; be able to compare ...
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03 - Toxicokinetics and Toxicodynamics (Toxicology for Chemists - Module 3)
This module is an introduction to toxicokinetics and toxicodynamics. The module is split into five lectures addressing: absorption, distribution, biotransformation, excretion, and toxicodynamics. Using these materials, students will be able to: explain and describe ADME; learn introductory biochemistry, chemistry, and anatomy to explain ADME; and explain and describe toxicodynamics. The lecture ...
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04 - Reaction Mechanisms (Toxicology for Chemists - Module 4)
This module gives an overview of the main reaction mechanisms seen in toxicology studies. Students will learn primarily about the main electrophilic reactions that bind toxicants to proteins, in addition to a brief introduction to reactive oxygen species and radical reactions. This module pairs well with Module 11 – Structure-Activity Relationships, and these lecture slides are also included for ...
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06 - Toxicity of Metals (Toxicology for Chemists - Module 6)
This module is a good introduction to metal toxicity. Students will learn about the toxicity of metals in the body, metal pollution, the difference between metals and metalloids, mechanisms of heavy metal toxicity, and factors that affect metal toxicity. These lecture slides are heavily case-study based and provide an applied outlook on the chemistry with reference to many global incidents and ...
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07 - Environmental Fate, Persistence, and Biodegradation (Toxicology for Chemists - Module 7)
This module contains an introduction to the concepts of fate, persistence, and biodegradation. Students will learn about: classes of molecules that persist in the environment; different types of degradation and their critical role in the environment and society; and parameters that affect biodegradation rate. Part II of this module is a full case study entirely based on the Deepwater Horizon oil ...
![overview on green chemistry assignment pdf toxicology for chemists curriculum orange cover with white text](https://gctlc.org/sites/default/files/styles/learning_object_library/public/2023-08/tox-cover-final_8.png.webp?itok=DknEzzCh)
08 - Environmental Toxicology (Toxicology for Chemists - Module 8)
This module serves as an introduction to the principles of environmental toxicity: air pollution, water pollution, and chemical transport and fate. Using these materials, students will learn examples of pollutants and their effects on human health and the environment through multiple case studies and in-class discussions. These lecture slides comprise mostly case studies and provide a good outlook ...
![overview on green chemistry assignment pdf toxicology for chemists curriculum orange cover with white text](https://gctlc.org/sites/default/files/styles/learning_object_library/public/2023-08/tox-cover-final_17.png.webp?itok=IvVkYY_G)
09 - Ecotoxicology (Toxicology for Chemists - Module 9)
This module provides an introduction to ecotoxicology, an overview of exposure and thresholds, an overview of the main concepts and scales of ecotoxicology, and some applications of ecotoxicology. Using these materials, students will learn: the history of ecotoxicology; why ecotoxicology is important to sustainability; effects on levels of biological organization; relations to hazard and risk ...
![overview on green chemistry assignment pdf toxicology for chemists curriculum orange cover with white text](https://gctlc.org/sites/default/files/styles/learning_object_library/public/2023-08/tox-cover-final_18.png.webp?itok=UBlzewnS)
10 - Predictive Toxicology (Toxicology for Chemists - Module 10)
This module provides an overview of computational methods to predict the toxicity of chemicals. Students will learn an updated overview of the latest methods that have been successfully applied to predict toxic effects of chemicals, in addition to understanding the outlook towards at the nexus of computational sciences and toxicology. Particular emphasis is placed on carbon-based toxicants ...
![overview on green chemistry assignment pdf toxicology for chemists curriculum orange cover with white text](https://gctlc.org/sites/default/files/styles/learning_object_library/public/2023-08/tox-cover-final_19.png.webp?itok=pMUmpp2L)
11 - Structure-Activity Relationships (Toxicology for Chemists - Module 11)
This module connects the structure of molecules to their activity in biological systems. Students will be able to: identify physicochemical properties related to ADME; identify and rationalize relationships between physiochemical properties and biological activity in different species; apply pre-screening tools for acute and chronic human and ecological endpoints based on physicochemical ...
![overview on green chemistry assignment pdf toxicology for chemists curriculum orange cover with white text](https://gctlc.org/sites/default/files/styles/learning_object_library/public/2023-08/tox-cover-final_20.png.webp?itok=KEe7Umkk)
12 - Case Studies, ChemToxTidbits, “Grab Bag” Folder (Toxicology for Chemists - Module 12)
Don’t have much time to prepare your lectures? Don’t know where to start with incorporating toxicology into existing class lectures or assignments? Not sure if you’re ready to adopt a full module? Do you just want access to the case studies, in-class assignments, homework assignments, and ChemToxTidbits slides? This folder contains all of these materials in a format easily accessible to you so ...
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12 Principles of Green Chemistry
This is a poster of the 12 Principles of Green Chemistry. The poster can be printed out in varying sizes and is designed to be used as a teaching tool in a classroom, laboratory or manufacturing setting.
Please select the file below based on your audience location. For those in North America please use the MilliporeSigma file, for those outside North America please use the international Merck ...
![overview on green chemistry assignment pdf logo with green flask with green gem superimposed on part of flask](https://gctlc.org/sites/default/files/styles/learning_object_library/public/2023-10/logo-with-green-flask-with-green-gem-superimposed-on-park-of-the-flask_3.png.webp?itok=T4QMBDLo)
A Green Alternative to Aluminum Chloride Alkylation of Xylene
The alkylation of aromatic compounds is a very important industrial process. Typically these alkylations are performed using strong Lewis acids like aluminum trichloride as catalysts. However, the use of these catalysts often requires an aqueous work-up to remove the aluminum and also leads to mixtures of products due to carbocation rearrangement.
By using graphite this greener alkylation ...
A Green Nucleophilic Aromatic Substitution Reaction
This laboratory activity focuses on the tie-dyeing process as a safer alternative to nucleophilic aromatic substitution (SNAr) reactions for an introductory organic chemistry laboratory. The simple and straightforward experiment provides students with an opportunity to gain practical experience in conducting a chemical reaction in a real-world context while applying concepts of design for ...
![overview on green chemistry assignment pdf logo with green flask with green gem superimposed on part of flask](https://gctlc.org/sites/default/files/styles/learning_object_library/public/2023-10/logo-with-green-flask-with-green-gem-superimposed-on-park-of-the-flask_12.png.webp?itok=Ox76Hghw)
A Green Polymerization of Aspartic Acid for the Undergraduate Organic Laboratory
Because of the ubiquity of polymers, chemists are looking for ways to make polymers renewable, biodegradable, and with less waste. In this laboratory chemistry students will have the opportunity to make poly(aspartate), a polymer that fulfills all the abovementioned goals.
The synthesis of this condensation polymer starts by simply heating neat aspartic acid for two hours to form poly(succinimide ...
A Green(er) Redox Reaction
Green chemistry is an approach to practicing chemistry that strives to reduce or eliminate the use and generation of hazardous substances. This focus on safety and environmental responsibility must always refer to a baseline measure, meaning that reactions can never be “green” but instead can always be “greener”.
This lab provides a great example of a greener approach to teaching reduction ...
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A Green, Guided-Inquiry Based Electrophilic Aromatic Substitution for the Organic Chemistry Laboratory
This exercise demonstrates the regioselectivity of substituted aromatic systems while reducing the amount and hazards of the waste produced by the class. Although typical iodinations involve either high amounts of derivatization (i.e., nitration, then reduction to aniline, formation of diazonium, then ionization) or use of hazardous/expensive reagents (iodine and mercury acetate, bis(pyridine ...
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A Greener Approach for Measuring Colligative Properties
This experiment teaches students the concept of colligative properties using renewable, benign, and biodegradable materials. Rather than using conventional solvents with high cryoscopic constants (which are oftentimes aromatics), fatty acids are used to explore freezing-point depression. By monitoring the change in freezing points of solutions with varying solute concentrations, students will be ...
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A Greener Chemiluminescence Demonstration
This demonstration shows students a long-lasting, chemiluminescent reaction in light sticks without the toxic solvents. The instructor must prepare the chemiluminescent reagent, divanillyl oxalate, in a one-step synthetic procedure or can have the students prepare the reagent as part of an organic chemistry experiment.
Solvents acceptable for the chemiluminescence reaction are ethyl acetate or ...
A greener tetraphenylporphyrin synthesis and metallation: an undergraduate teaching experiment
In this experiment, 5,10,15,20-tetraphenyl-21H,23H-porphyrin (H2TPP) is synthesized on the microscale using an optimized procedure with a research-grade microwave apparatus (CEM Discover). This experiment can also be extended to the para-substituted phenyl derivatives.
Metalloporphyrins, with an array of metals, can then be synthesized using greener routes including mechanochemical methods (with ...
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A guidebook for sustainability in laboratories
This guidebook aims to improve lab users’ everyday practices to become more sustainable. Specifically, this guidebook provides practical suggestions on how to effectively use lab instruments and resources and how to acquire data. We provide advice to labs covering disciplines such as biology, chemistry, computational science, engineering, life sciences, materials sciences, medicine, pharmacy, and ...
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A Microscale Heck Reaction In Water
This laboratory experiment features the palladium-catalyzed Heck synthesis of (E)-4-acetylcinnamic acid from 4-iodoacetophenone and acrylic acid by mid-level undergraduates. Traditional Heck reaction organic solvents (e.g. acetonitrile) and base (e.g. triethylamine) are replaced by water and sodium carbonate respectively. This approach introduces fundamentals of green chemistry (aqueous and ...
A Mole of Rice
The mole is a very large number used to measure the number of very small objects in chemistry. Using the mole to describe the number of a macroscopic object is not practical.
Earth’s diameter (see link below)
How much rice does China grow? (see link below)
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A promise to a sustainable future: 10 years of the Green Chemistry Commitment at Beyond Benign
Green chemistry education is a fundamental tool for the achievement of a sustainable future at the molecular level. It allows the development of a scientific workforce and knowledgeable citizenry with the skills to choose, assess, and further design more benign processes for human health and the environment. In 2007, Dr Amy Cannon and Dr John Warner co-founded a non-profit organization known as ...
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A Solvent-Free Baeyer–Villiger Lactonization for the Undergraduate Organic Laboratory: Synthesis of γ-t-Butyl-ε-caprolactone
The transformation of ketones into esters using peroxy acids was first reported in 1899. Since then, the Baeyer-Villiger oxidation has found itself an integral part of the organic chemist's toolkit. This modified Baeyer-Villiger is a great example of how a classic reaction can be made significantly greener. By eliminating the solvent you can avoid the hazards associated with dichloromethane (the ...
Acids, Bases, and pH
This lab is intended to introduce students to the concepts of acids, bases, and pH. Students determine the best suitable natural indicators to test the pH of the various household products and substances.
Add ocean acidification to your existing lessons
This resource provides an overview of ways to discuss ocean acidification with high school students (14-16 years), including connecting increasing levels of carbon dioxide in the atmosphere with absorption by the oceans and the resulting increase in ocean pH. Topics include understanding pH as a logarithmic scale, the nature of acids (strong vs. weak), and connecting these topics to the U.N ...
Add sustainable management of water to your existing lessons
This page through the Royal Society of Chemistry (RSC) website provides a collection of curriculum resources for high school-level students focused on the sustainable management of water. It includes a downloadable practical and simple microbiology experiment looking at the antimicrobial properties of halogens, as well as additional reading and information for putting water scarcity and management ...
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Alkene Isomerization Using a Solid Acid as Activator and Support for a Homogeneous Catalyst
In this laboratory experiment, students explore the use of an immobilized Ni[P(OEt)3]4H2SO4 catalyst system to study the isomerization of 1-octene to trans- and cis- 2-octene. Nafion-H+ is a solid acid ion exchange polymer that both activates the air-sensitive transition metal catalyst and immobilizes the cationic species that can be characterized by UV-vis spectroscopy within the polymer matrix ...
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An Asymptotic Approach to the Development of a Green Organic Chemistry Laboratory
This article provides a rationale and stepwise process for evaluating and improving the "greenness" of an undergraduate organic chemistry laboratory curriculum. After emphasizing the educational value of sharing this process with students, effective risk assessment is discussed as an important tool for both evaluating and redesigning laboratory exercises. The greening process is illustrated by ...
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An Inexpensive Aquarium Pump Water Recirculator for the Teaching Laboratory
The design and operation of a simple and inexpensive water recirculator is described, which can replace wasteful running water "tap-to-drain" applications such as providing cooling to Liebig-type (water jacket) condensers. The recirculator uses an inexpensive and easily acquired aquarium pump placed within a large plastic jar or bucket. Data is provided for the estimated water saved per hour ...
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An Innovation Studio Leans into the Power of Green Chemistry
Schoolab is an innovation studio that pairs student teams with corporate partners to solve real-world business & design challenges. In the US, they run a program at the University of California Berkeley called "Deplastify the Planet."
Recently it became clear that the sustainable design solutions they were trying to create would benefit tremendously from taking their design thinking all the ...
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Animal Adaptations & Engineering Design: Lesson 04: Building with Biomimicry
Using biomimicry for ideas, scientists and engineers can create sustainable solutions for a vast range of problems. Scientists consider how plants and animals create a material or perform a process, and engineers then use that information to create inventions that are scalable to meet the needs of people
Antibacterial properties of the halogens
This two-part microbiology practical investigation introduces students to the antibacterial properties of halogen solutions and their use for water treatment from contaminated sources.
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Approaches to Incorporating Green Chemistry and Safety into Laboratory Culture
This is an open access article linked from the Journal of Chemical Education article. It highlights a systems thinking approach to incorporating green chemistry and safety into laboratory culture. This article, emphasizes how framing green chemistry through the lens of systems thinking can build a culture of safety in the laboratory.
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Aqueous-Phase Palladium-Catalyzed Coupling. A Green Chemistry Laboratory Experiment
This experiment highlights both the importance of palladium-catalyzed coupling reactions and the need for finding greener solvents. The aqueous-phase coupling of iodobenzene and diethylphosphite is a great example of how a reaction can be made greener with a relatively straightforward modification. By simply sulfonating triphenylphosphine, students will be synthesizing a water-solubilizing ligand ...
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Assessment of Student Knowledge of Green Chemistry Principles
The following abstract is excerpted from the linked external resource.
"As implementation of green chemistry into university-level courses increases, it is vital that educators have a tool to rapidly measure student knowledge of green chemistry principles. We report the development of the Assessment of Student Knowledge of Green Chemistry Principles (ASK-GCP) and evaluation of its sensitivity ...
Biomimicry Matching Game
Biomimicry is the science and art of emulating nature’s best biological ideas to solve human problems. The natural world is made up of very good green chemists. Consider animals and how they make their own shelter and get all the food they need from other things in nature. This is all done without having to use any gas or electricity or taking more than they need, and they produce little waste or ...
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Blue is the new green: Valorization of crustacean waste
Annually, large amounts of marine biomass waste are generated around the world. In the case of crustaceans, an opportunity is lost to convert these chemically rich streams into essential and industrially relevant materials as these residues are often landfilled or directly discarded in the environment. Current processes to produce chemicals from marine biomass rely on wasteful, chemically- and ...
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Bringing State-of-the-Art, Applied, Novel, Green Chemistry to the Classroom by Employing the Presidential Green Chemistry Challenge Awards
In 1995 President Clinton introduced the Presidential Green Chemistry Challenge (PGCC) Awards Program. The program was created to acknowledge companies and individuals who research and develop technologies "that promote pollution prevention and industrial ecology through a new EPA Design for the Environment partnership with the chemical industry." In this article, Dr. Michael Cann discusses two ...
Calorimetry
Three “coffee-cup” calorimetry experiments: 1) Use of the Law of Dulong and Petit to identify an unknown metal 2) Measurement of the enthalpy of sublimation of dry ice 3) Exploration of the relationship between surface area and the rate of heat transfer and the amount of heat transferred
Featuring contributions from Tamara Fitzjarrald
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Can Biodegradable Materials Replace Plastic as Protective Food Packaging?
Many foods, such as fresh fruits, vegetables, or eggs, are packaged in plastic to protect them from damage during handling and transport. But is plastic the best choice? What if a more sustainable and biodegradable material could replace it? Researchers have begun exploring hydrogels—squishy materials that can hold a lot of water—as alternative packaging materials. In this science project, you ...
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From the contents:Foreword. Preface * 1. Introduction * 2. Designing a Green Synthesis * 3. Basic Principles of Green Chemistry * 4. Green Chemistry in Day-to-Day Life * 5. Environmental Pollution ...
TECHNO WORLD. A T extbook of. Green Chemistr y. Sankar Prasad Dey, Ph.D. (J.U) Associate Professo r, Department of Chemistry (UG &PG), Behala College, Parnashree, Kolkata-700060, I ndia. Former ...
Designing Safer Chemicals. Chemists are molecular designers; they design new molecules and new materials. Green Chemists make sure that the things that we make not only do what they're supposed to do, but they do it safely. This means that it's not only important how chemists make something, it's also important that what they make isn't ...
FUTURE CHALLENGES. Dirgha Raj Joshi 1* and Nisha Adhikari 2. 1 College of Pharmacy, Yonsei University, 85 Songdogwahak-ro, Yeonsu-gu, Incheon 21983, Republic of Korea. 2 College of Pharmacy ...
Protein Testing. Automated protein tagging technique. Tags amino acids commonly found in proteins. Employs non-toxic solutions. Generates no hazardous waste. Replaces hazardous materials and high temperatures in traditional methods. Applications in the food and pet food sectors. CEM Corporation.
All the materials presented in this book are updated. Clarity rating: 5. The text is written in simple language that should be helpful for the readers to understand the topic. Consistency rating: 4. The six chapters are well-aligned, and the whole concept of green chemistry has been thoughtfully presented in this book.
• "green chemistry" focuses on reducing or eliminating the use or generation of hazardous substances in the design, manufacturing and application of chemical products, guided by the well-known 12 green chemistry principle; • "sustainable chemistry" is evolving as a more holistic complementary concept which embraces green chemistry;
Green chemistry plays a vital role in minimizing the hazards associated with chemical preparation, reactions, and products in daily life. Therefore, it becomes essential to understand students' attitudes towards green chemistry and its practical application, particularly among chemistry students. This study aims to examine students' perceptions ...
This book summarizes fundamentals and advanced topics of green chemistry and highlights the importance and impact of green chemistry over traditional synthetic methods. It discusses about the importance and scope of the catalytic protocols in green chemistry and their application in daily life. Alternate green energy approaches discussed in ...
The Twelve Principles of Green Chemistry, continued 6) Energy requirements should be recognized for their environmental and economic impacts and should be minimized. 7) A raw material feedstock should be renewable rather than depleting whenever technically and economically practical.
Structured around the well-known 12 Principles, and firmly grounded in real-world applications and case-studies, this book shows how green chemistry is already being put into practice and prepare them to think about how they can be incorporated into their own work. Targeted at advanced undergraduate and first-year graduate students with a ...
Reading Assignments (due Thursdays): Week 1: The 2011 Green Chemistry Awards- note: you are only responsible for pages 1-7, the winners. The rest is purely bonus material. Do NOT print all 64 pages unless you really want them!
Learning Outcomes. By the end of this course, students will be able to: Develop and demonstrate knowledge pertaining to the background and development of Green Chemistry (Capability 1 and 2) Understand and apply knowledge of the common metrics used in Green Chemistry applications. (Capability 1, 2 and 3)
An effective integration of these catalytic technologies in organic synthesis is truly the key to success. An elegant example is the Rhodia process for the manufacture of the flavor ingredient, vanillin [30]. The process involves four steps, all performed with a heterogeneous catalyst, starting from phenol (Fig. 1.48).
Review of 12 Principles of Green Chemistry in Practice. Anita Ivanković 1, Ana Dronjić 1, Anita Martinović Bevanda 2, Stanislava T alić 2. 1 Faculty of Agronomy and Food Technology, University ...
2 Assignments: Quizzes: There will be two types of quizzes: In-class, unannounced pop quizzes on reading assignment for the day and online quizzes based on flipped lecture content. Make-ups for missed in-class quizzes will be available to students with documented excused absences only.
Use green and sustainable chemistry innovation to improve resource eficiency, pollution prevention, and waste minimization in industrial processes. Reduce chemical releases throughout the life cycle of chemicals and products. Consider social factors, high standards of ethics, education and justice in chemistry innovation.
Inherently Safer Chemistry for Accident Prevention Substances and the form of a substance used in a chemical process should be chosen to minimize the potential for chemical accidents, including releases, explosions, and fires. 2. "Green Chemistry is sustainable chemistry"- Explain the statement Hints: Green chemistry is sustainable ...
Green chemistry can also be described as. Sustainable chemistry. Chemistry that is benign by design. Pollution prevention at the molecular level. All of the above. Focus on processes and products that reduce or eliminate the use of polluting substances. Any synthesis, whether performed in teaching, laboratories or industries should create none ...
Redesigning Organic Synthesis. Bharati V Badami. Green chemistry is the utilization of a set of principles that will help reduce the use and generation of hazardous sub-stances during the manufacture and application of chemical products. Green chemistry aims to protect the environment not by cleaning up, but by inventing new chemical processes ...
imate disposal. Green chemistry is also known as sustain. en Chemistry: Prevents pollution at the. ecular level. Is a philosophy that applies to all areas of chemistry, not a single discipli. of chemistry. Applies innovative scientific solutions to real-world environm. al problems. Results in source reduction because it prevents the generatio.
Green Chemistry BG 5th Sem KU (Batch 2016) or eliminate the use and pr. not lead t. prevention approach, while as en. ironmental chemistryapproach is a treatment approach. Since prevention is better than cure, we may say. reenchemistry is better than environmental chemistry.To. evelop a perfectly green c.
Welcome to the GCTLC Library. Use the search and filter options below to find green chemistry education resources and curriculum materials from community members from across the world. You can also submit a new resource to the library. For information for authors and reviewers, please consult the Guidelines for Submission and Review of Learning Objects.
Green Chemistry Cutting-edge research for a greener sustainable future ˜˚˛˝˙ˆˇ˘˜ ˛ ... This critical review provides an overview of the sustainability outcomes associated with flow ... The missing 7 assignments for costs and LCA, does not (necessarily) mean that there . Page 43 of 58 Green Chemistry *UHHQ